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Schichtungsphänomen, Paradoxon und weitere Phänomene konnten 2000 im Zuge der Hoffmann-Studien aufgedeckt werden über Trocknung und Flüssigkeitswiederaufnahme an menschlichen Zähnen. In diesem Zusammenhang wurden dafür absolute Vergleiche der Farbwerte aus

visueller und messtechnischer Zahnfarberfassung vorgenommen und die Werteunterschiede analysiert.

André Hoffmann hat die Entstehung der Zahnfarbe systematisch und höchstpräzise u. a. an menschlichen Zähnen und dentalen Farbringen mit Hochpräzisionsmesssystemen und mit eigens entwickelten Hochpräzisionspositionierungssystemen erforscht und insbesondere im Jahre 2000 seine neuen Erkenntnisse vorgelegt und veröffentlicht und in den Folgejahren konkretisiert. Der Pionier im Bereich der optischen Technologien dürfte im Zuge seiner wissenschaftlichen Grundlagenforschung die wesentlichen Einflussfaktoren isoliert und eindeutig quantifiziert haben. Dazu gehören beispielsweise das Licht bzw. Messlicht und die Lichtarten verschiedener Farbtemperaturen, die Strahlengänge des Lichtes bzw. die Messgeometrien (Orte von Lichtquellen und Sensoren in Relation zur Messprobe), der Beobachtungswinkel (2°, 10°), die Größe der Messfläche und Messöffnung, die Glanzwirkung, der Flüssigkeitsgehalt (mit wissenschaftlichem Beweis des Zusammenhanges zwischen Flüssigkeitsgehalt und Zahnfarbe), Wirkung von Trocknung und Flüssigkeitswiederaufnahme (Dehydratation, Rehydrierung), der Anteil des Flüssigkeitsgehaltes an der Glanzwirkung, die Subjektivität von visueller Bestimmung, Kronenkrümmung, Systemart (Spektralphotometer, Dreibereichsfarbmesssystem), Messmodus (Kontakt oder Non-kontakt-Modus), Messsystem-Objekt-Relation, Positionierung, Wiederholbarkeit bzw. Reproduzierbarkeit. Zudem wurden subjektiv-visuelle Bestimmungen und objektivierte Messungen in Subjektiv-objektiv-Vergleichen über Wertevergleiche nachgegangen. Alle diese Einflussfaktoren sind nicht nur an feuchten, sondern auch an trockeneren (verschiedene bestimmte Trocknungs- bzw. Rehydrierungszustände) und trockenen Zähnen anhand u. a. der Helligkeit (L*), von Farbmesswerten, wie beispielsweise a*, b*, C*, h, ΔE, des Metamerieindex, von Spektralwerten, von Zahnfarbproben und von Zahnfarbräumen analysiert.

Im Rahmen dieser Erkundung konnten Phänomene (beispielsweise Änderungen und Brüche im Verhalten sowie hochindividuelle Entwicklungen der Farbwerte, Paradoxes zwischen den Werten subjektiver Bestimmung mittels Zahnfarbproben und den Werten objektivierender Messungen) aufgedeckt und Einblick in die Farbdynamik durch De- und Rehydratation gewährt werden. Die Entwicklung der einzelnen Farbmesswerte ließ beispielsweise Rückschlüsse über den Flüssigkeitsfluss durch den Zahn und seine Gewebe insbesondere bei Trocknung und Flüssigkeitswiederaufnahme zu und gab Auskunft über das zeitliche Ausmaß dieser Prozesse.

Auf Basis dieser Datenlage hatte Hoffmann mehrere Verfahren für die Forschung und Anwendung in der Praxis entwickelt, Innovationen vorgeschlagen und für machbar eingestuft, wie beispielsweise das trocknungsprotektive Monitoring zur Vermeidung von Devitalisierung bei zahnmedizinischer Behandlung, eine Rekonstruktion der Farbe von natürlich feuchten Zähnen an bereits angetrockneten, die Identifizierung von Lebenden und Toten über den «dentalen Fingerabdruck» und für die Rechtsmedizin eine neue Methode zur Todeszeitbestimmung. Zudem beschrieb er eine zeitliche Trocknungsgrenze, bis zu der noch relativ natürliche, passende Farbwerte zu erhalten sind und nach der keine Farbbestimmung mehr erfolgen sollte, und er legte die Flüssigkeitswiederaufnahmezeit nach Ende der Trocknung fest, die gewartet werden muss, um wieder eine natürliche Zahnfarbe zu erhalten …

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